2010年11月5日 星期五

Polyurethane Glossary

Polyurethane Glossary



Density

Density is weight per unit volume, weight/volume, and is expressed as lbs/ft3 (pcf).
Density is usually measured in grams/cm3 and multiplied by 62.4 to convert to lbs/ft3 (pcf).
Density can be obtained from any sample size. Density is not related to pore size, i.e., coarse pore and fine pore foams can have equal densities.
Density is not a measure of firmness, stiffness, or load bearing capacity. That is defined by Indentation Force Deflection (IFD) or Compression Force Deflection (CFD).

Indentation Force Deflection (IFD)

IFD (previously ILD) is one test method to determine load bearing capacity (firmness or stiffness), and is expressed in pounds force per 50 in.2 at a given percent deflection of the foam.
For example: P215-50, FHA grade carpet cushion foam has a target IFD of 50 lbs/50 in2 at a deflection depth of 25% of the original thickness of the sample after a rest period of one minute, 25%R.
To obtain the 25%R value, a 50 in.2 circular indenter platen is driven into a 15” x 15” x 4” foam sample, stopping when it reaches a deflection of 1”, 25% of the 4-inch thickness. The testing device records the force in pounds required to hold this foam indented after one minute. The higher the force reading, the higher the load bearing capacity of the foam. This result can be reported in metric and the sample size can be varied.
Sag Factor (Modulus) is the ratio of the 65%R IFD to the 25%R IFD values and is expressed in real numbers with one decimal. Sag factor gives an indication of cushioning quality. A high value indicates a resistance to “bottoming out.”
Recovery Ratio is the ratio of 25%R IFD released to 25%R IYD initial when measuring IFD values at 25% deflection, 65% deflection, and then released back to 25% deflection. Recovery ratio is expressed as a percentage.
Guide Factor is the ratio of 25% IFD to density and is expressed in whole numbers. Guide factor is useful in determining the relative firmness of foams with different densities. It is also used to compare the economy of foams. The higher the guide factor, the more economical the foam because you get a firmer foam with a lower density.

Compression Load Deflection (CLD)

CLD is also a measure of firmness and is expressed in pounds per square inch (psi), at a given percentage deflection.
The sample size is 2” x 2” x 1” thick. The entire sample is compressed under the 50 in2 indenter platen in this test. The procedure is the same as IFD. Record 25%R & 65%R values. It is common practice on foam specifications is to specify only the 25%R-value.
Both IFD & CFD can be tested at 50%R or any other deflection point based on customer / supplier agreement.

% Compression Set

% compression set is a measure of the permanent deformation of a foam after it has been compressed between two metal plates for a controlled time period and temperature condition. The standard conditions are 22 hours at 70°C (158°F) The foam is compressed to a thickness given as a percentage of its original thickness, usually 50%. Compression set is expressed as the percentage of its original thickness that remained “set”. For example: If a 2” x 2” x 1” sample measured 1.00 inch before compression and 0.95 inch after the test, it is reported to have a compression set value of 5%, i.e., it did not recover 5% of its original thickness.

Tensile Strength

Tensile strength is a measure of the amount of force required to break a 1/2 square inch area of foam as it is pulled apart. Tensile strength is expressed in pounds per square inch (psi). The tensile sample is die cut to a dumbbell shaped, 6” x l” x 0.5” thick.

Elongation

Elongation is a measure of the extent to which the foam can be stretched before it breaks and is expressed as a percentage of its original length. Elongation is measured at the same time, as tensile strength is determined; therefore, the sample size is the same.

Tear

Tear strength is a measure of the force required to continue a tear in foam after a split has been started and is expressed in pounds per linear inch (pli).
The sample size is 6” x l” x l” thick.
Tear strength is an important property when the foam will be sewed or stapled in an application.

Permeability

Permeability is the measure of the volume of air per minute that can be pulled through a sample of foam and is expressed in cubic feet per minute.
The sample size must be at least 4” x 4” to fit over the opening of the Frazier permeability device.
The thickness varies with the product. When possible, the permeability is tested on the application thickness.

Impact Resilience (Ball Rebound)

Impact Resilience is a measure of elasticity, bounce, or springiness of foam and is expressed as a % of return, or % resilience.
The sample size is 4” x 4” x 2”
To obtain % resilience a 16.3 gram, 5/8 inch, steel ball is dropped 18 inches onto the foam through a clear plastic tube with every 5% return calibration marked. Three drops are executed and the averages of the three readings are equal to the % of the return of the ball to its original height.

Clickability

Clickability is the rating of a foam’s ability to recover from a die cutting operation. Foams are rated as having a good, fair, or poor click property. Click is tested on a one-inch piece of foam by die-cutting a tensile specimen and observing the initial recovery and then the recovery after one minute. What is observed is the sharpness of the
edges of the tensile part and the one-inch foam sheet it was cut from. Also, the height recovery after the compression of the die cutter is noted.

Weldability

Weldability is the opposite of clickability. If foam has a poor click rating it is said to weld, i.e., the top and bottom edges of the die cut part stick together.

Thickness

Thickness is the measurement of the distance between the top and bottom surfaces of a sheet of foam and is expressed in mils or inches. For example, 1/8 of an inch equals 0.125 inch or 125 mils; therefore, one inch is equal to 1,000 mils.
Foam thicknesses are measured or gauged by micrometers. Pin, circular plate, hydraulic micrometers are used for measuring thickness on foam. It is necessary to have as little force placed on the foam surface by the micrometer as possible. It is advisable to place a metal plate underneath the foam sample for a stable base.
Foam is measured in board feet. A board foot of foam is equal to a 12”x12”xl” piece of foam and this is equal to 1/12 of a cubic foot of foam. This is the commonly used measure in the foam industry.

Bond Strength

Bond Strength is a measure of the force needed to separate two substrates that are laminated together and are expressed in ounces.
The sample size is 8” x l” x thickness of the laminate.

Steam Autoclave Aging

Steam Autoclave Aging is a test treating the foam sample in a steam autoclave and retesting specific physical properties to detect appreciable deterioration of the foam after hot and humid conditions.
There are two sets of conditions that ASTM D 3574 specifies:
  1. 3 hours at 105 ± 3°C., and
  2. 5 hours at 125 ± 5°C.
Condition 1 is usually used for polyester foams and condition 2 is for polyether foams.

Dry Heat Aging

Dry Heat Aging is a test treating the foam sample in an air-circulating oven and retesting specific physical properties to detect appreciable deterioration of the foam in hot but dry conditions. This aging test is performed for 22 hours at 140°+ 1.2°C.

Fatigue

Fatigue is a measurement of the loss in load bearing capability and is expressed as a percentage load loss.
Three fatigue tests are:
  1. Static Fatigue: Measure the 25% and 65% IFD values. Deflect to 75% if the original thickness and keep deflected for 22 hours. Relax the foam for 30 minutes. Then retest IFD at 25% and 65% deflection points and calculate force loss.
  2. Roller Shear Fatigue: A stainless steel roller is used to dynamically fatigue a sample of foam for 8,000 or 20,000 cycles in 5 hours or 12 hours respectively. IFD values are also compared before and after fatiguing and a percent loss of load bearing capability is calculated.
  3. Constant Force Pounding Fatigue: A flat horizontal indenter foot is used to fatigue a foam sample for 8,000 cycles in 2 hours, or 80,000 cycles in 19 hours.
IFD values at 40% deflection are compared before and after fatiguing and the percent load loss is calculated.

Package Design Guide

This guide has been prepared to assist packaging designers in the selection and utilization of ETHAFOAM brand polyethylene foam and other Performance Foams products for protective packaging applications. It contains recommended considerations and procedures for the design and development of highly protective and cost-efficient packaging.
This information is offered to facilitate the process of designing and developing packing that provides the desired level of protection at the most reasonable cost. It is recommended that, once a package design has been determined, a prototype product-package combination should be developed and tested for performance prior to final inspection.

Preliminary Design Considerations

The first step in designing a protective packaging solution is the selection of a cushioning material that is appropriate for the application.
As a general rule, ETHAFOAM polyethylene foams are best suited to protect products which can be described as relatively high in value and moderately fragile. Keeping damage rates for products of this nature to a minimum requires a strong, resilient cushioning material that reliably protects against multiple impacts. In other words, care must be taken to select a cushioning material that is not damaged by initial impacts and recovers to maintain its cushioning protection against repeated shocks.
ETHAFOAM products are resilient in nature, giving them outstanding recovery characteristics that provide outstanding cushioning protection against repeated impacts. And ETHAFOAM products are available in a variety of strengths, making them suitable for protecting products ranging from just a few pounds up to hundreds of pounds in weight.

TEP ONE: Determine Product Fragility

The first step toward determining the amount of cushioning a product requires is to determine the amount of mechanical shock the product can survive on its own. There are several common terms for this, with "fragility" and "g-factor" being the most common.
Fragility is normally expressed in units of "g’s" and indicates the maximum deceleration the product can withstand without being damaged. The more fragile a product is, the lower its g-factor. The table below helps to illustrate this concept.

Approximate Fragility of Typical Packaged Articles

ClassTypical ContentsFragility
Extremely FragileMissile guidance systems, precision aligned test instruments15-25 g’s
Very DelicateMechanically shock-mounted instruments and electronic equipment (Shock mounts should be firmly secure prior to packaging. They are provided for in-service protection only.)25-40 g’s
DelicateAircraft accessories, electric typewriters, cash registers and other electronically operated office equipment40-60 g’s
Moderately Delicate     Television receivers, aircraft accessories60-85 g’s
Moderately RuggedLaundry equipment, refirgerators, appliances85-115 g’s
RuggedMachinery115 g’s and up 

Ideally, the fragility of a product is determined by subjecting it to a series of gradually more severe shocks (decelerations) in order to find the lowest severity impact that will damage the product. The highest deceleration, which did not cause damage, is then known to be the product’s g-factor.
It may be necessary to determine fragility levels for a product in various orientations, as it is not uncommon for a product to exhibit greater strength in one direction than another. Even very similar models should be tested individually as it’s seldom that fragility for one model may be safely assumed from another.
There is no substitute for fragility test data. Educated guesses as to a product’s fragility are often counterproductive to the design process. If the g-factor is estimated too high, and the product is unable to survive as much shock as anticipated, the packaging will be underdesigned and significant shipping damage is likely to occur. On the other hand, if the g-factor is estimated too low, and the product can actually withstand more shock than anticipated, the packaging will be overdesigned and unnecessarily expensive.

STEP TWO: Determine Conditions the Product Will Encounter

Once product fragility is determined, the packaging designer should next consider the handling and transportation environment the product will face.
To establish the amount of shock the product may encounter, it is necessary to determine the height from which the product may be dropped. Drop heights are generally established by the product’s weight, which usually reflect how the product will be handled.
The chart below shows typical drop heights for products of various weights, and may be used if you lack specific information about the handling likely to be encountered in your product’s particular distribution chain.

Typical Drop Heights

Weight Range (lbs)Type of HandlingDrop Height (in)
0-101 person throwing42
10-201 person carrying36
20-501 person carrying30
50-1002 person carrying24
100-250Light equipment18
250+Heavy equipment handling12
NOTE: Palletized products may receive drops of up to six inches.

STEP THREE: Calculate Fundamental Cushion Requirements

When product fragility (g-factor) and handling environment (drop height) have been determined, the procedure that follows can be used to determine the amount of functional cushioning material which will provide adequate protection for the packaged item.
By functional cushioning material, we mean that portion of the design which directly supports the load and functions to absorb shock during impacts. There may be additional material used in the design as well to connect functional cushioning parts together, facilitate pack assembly, etc. This procedure does not take into account such factors as the effect of the outer container or other effects that may take place inside the container.
Generally such effects are beneficial so that this procedure can confidently be used as a starting point to develop packaging that provides an assured level of protection and optimum cost-efficiency. To calculate functional cushioning needs it will be necessary to understand and use dynamic cushioning curves.

Using Dynamic Cushioning Curves: An Overview

Typical dynamic cushioning curve
A cushioning curve shows how a particular packaging material of a given thickness behaves at different impact conditions. Curves are generated by dropping a series of known weights onto a cushion sample from a specified height and measuring the amount of shock experienced by the weights as they impact the foam. In simple terms, this testing represents a product dropping on a cushion from a height likely to be encountered during shipment.
An idealized cushioning curve is shown below. It represents the cushioning performance of a cushioning material for a given combination of thickness and drop height. The horizontal axis represents a range of static loadings (in pounds per square inch) that packaged items might apply to the cushioning material. The vertical axis represents the shock experienced as the cushion is impacted. Curves are often presented for both first impact and multiple impact (average of drops 2-5) data. It is common to include data for several cushion thicknesses from a constant drop height on a single set of axes.
Cushioning curves for ETHAFOAM* products may be obtained by contacting your local Dow-authorized fabricator, your local Dow representative, or Dow’s Research and Development facility.

Using Dynamic Cushioning Curves:
An Example

Determining Cushion Thickness
24" drop height, 2-5 drop average
An object to be packaged is a 10-inch cube weighing 60 pounds with a fragility of 50 g’s. Since a product typically faces repeated impacts during shipment, you will probably wish to use multiple-impact data. The typical drop height for a product of this weight may be estimated from the chart below as 24 inches, however specific knowledge of shipping conditions or corporate standards may dictate a different choice for drop height.
First, obtain the cushioning curves for the cushioning material you wish to use. Locate curves that represent multiple impact data from a drop height of 24 inches. One such set of curves is shown here.

Determining Thickness

Using the chart below as a reference, locate our product’s fragility level (50 g’s) on the vertical axis of the figure, and draw an imaginary horizontal line across the chart at this level.
This separates the chart into two sections:
  • our fragility line and lower, where the packaged item will be able to survive the anticipated shock level, and
  • the section above our line where the shock levels are high enough to damage the product
Note that in this example, a 1-inch thickness of this cushioning material will not protect the item down to 50 g’s because the entire 1-inch curve is located above the 50 g line, in the "damage" zone. All of the other curves, representing cushions 2 inches thick and greater, have portions down in the "no damage" zone, and thus can be used. In most cases, shipping and handling considerations provide a strong cost incentive to design as small a package size as possible, so the thinnest cushion thickness which will do the job is most often selected. In this case, we will choose a thickness of 2 inches.

Determining Static Loading and Bearing Area

Determining Static Loading Range
24" drop height, 2-5 drop average
Only a portion of the 2-inch cushion curve can be used to protect our product to 50 g’s. As seen below, the useable part of the curve is bounded by a static loading of 0.3 psi at the low end, and 1.4 psi at the high end. This tells us that, with a 2-inch cushion, we can apply a static loading anywhere within this "cushioning range" and still protect to 50 g’s or lower.
We now must choose a static loading to use within this range and design our cushions. The highest static loading value within the cushioning range will result in the most economical design because it will use less cushioning material to provide adequate protection, thus lowering design costs. Continuing with our example will illustrate how.
Once we have selected a static loading, we can calculate how many square inches of foam in our chosen thickness we’ll need to support and protect any side of the packaged product. In most cases it will be necessary to design a cushion to protect each of the faces of the product.
The cushion bearing area is easily calculated as the product weight divided by our chosen static loading. In this example, we have an allowable static loading range of 0.3 to 1.4 psi. If we were to choose to design with a static loading at the lower end of our range, 0.3 psi, we would divide our 60 pound product weight by 0.3 psi and find that we would need to support our product with 200 square inches of foam to produce a design which loads the foam to 0.3 psi.
If we were to choose the higher loading value of 1.4 psi instead, we would divide 60 pounds by 1.4 psi and find that only 43 square inches of foam are necessary to support the product at this higher loading. This is a 78.5% reduction in cushioning material compared to designing at 0.3 psi. You can imagine the cost savings that can result.
The use of higher loading values to optimize designs cannot be overemphasized. As a general rule, if you can double or triple the loading value and still not exceed your product fragility level, you can reduce your cushion usage by one-half to two-thirds. As a result, total material costs will be minimized.
Note that it may be possible to use even a smaller volume of foam by increasing thickness somewhat and taking advantage of the higher loading (and smaller bearing area) this allows. The resulting increase in shipping and handling costs due to package size increase is often greater than the saving in cushion material costs, so designing to the minimum thickness is the general practice.
By repeating this procedure with several materials, you can quickly generate comparisons, which will allow you to strike an economical balance between material cost and package size.

STEP FOUR: Recognizing Design Constraints

In most cases, the design approach we used in step three, i.e. using the highest possible static loading, will produce economical designs which adequately protect your packaged product. There are three constraints that must be checked however, to be sure this loading will not create other problems: compressive creep, cushion buckling, and extreme temperature effects.

Consider Compressive Creep

Compressive creep is the gradual loss of thickness a material may experience if placed under a constant load for an extended period of time. Significant compressive creep will result in the packaged product loosening in the cushion and becoming vulnerable to excessive movement inside the package during shipment.
As a general rule, creep of 10% is recognized as a practical upper limit. In some cases creep losses of over 10% in thickness have been shown to result in a significant loss of cushion performance.
Should it be found that creep in excess of 10% is anticipated, designers should recalculate the functional foam requirement using a lower static-loading figure. Spreading the loading over a larger area will reduce compressive creep.
The recommended loading limits to avoid excessive creep for various ETHAFOAM* polyethylene foam products are shown in below. Published dynamic cushioning data on ETHAFOAM cuts cushioning curves off at these limits to prevent you from inadvertently exceeding them.
These limits are believed to be adequate for temperatures encountered in a normal shipping environment. If exposure to excessive temperatures above 120°F are anticipated, lower loadings may be desirable. Consult product data sheets for compressive creep data on individual products.

Recommended Loading Limits for ETHAFOAM Brand Product

MaterialStatic Loading Limit
ETHAFOAM Nova1.5 psi
ETHAFOAM Select2.0 psi
ETHAFOAM 220, 4101, M12.5 psi
ETHAFOAM HS-45, M35.0 psi
ETHAFOAM HS-600, M410.0 psi
ETHAFOAM HS-900, M520.0 psi


Consider Cushion Buckling

Buckling Coefficients for ETHAFOAM 220 at Various Static Loadings
 
Buckling Coefficients for ETHAFOAM Select at Various Static Loadings
 
Buckling Coefficients for ETHAFOAM Nova at Various Static Loadings
 
Typical values, not product pecification limits.
Note: for higher strenght, higher density ETHAFOAM products, the use of a constant buckling coefficient (W/T) of 0.75 is recommended.
Buckling is the non-uniform compression of a cushion. When buckling occurs, the energy of the impact is not transferred evenly throughout the cushion and more shock is transferred to the package contents. Buckling usually occurs when the cushions become too tall and thin.
Buckling is actually less of a problem with ETHAFOAM* products than with many other cushioning materials. Yet it is one more factor you have to consider when designing a package. By using the charts and formulas presented below, you’ll be able to account for buckling in your designs and prevent any potential problems.
The tables help determine when the shape of the cushions can cause non-uniform compression, or buckling. They provide width-to-thickness coefficients for different static loading values and enable the designer to check for buckling potential.
To use the charts, determine the static loading (in psi) your product places on the cushion (divide product weight by surface area). Next, find the static loading value on the horizontal axis of the chart and read up to where the curve crosses it to find the buckling coefficient.
Next, multiply this coefficient by the thickness of the cushion to determine how wide the cushion must be to resist buckling. The example below will help illustrate how the chart and formula are used.
In cases where you must increase bearing area to avoid buckling, this results in decreased static loading. Check to see if this brings you into an appropriate loading range for the next lower strength grade of ETHAFOAM polyethylene foam, as it may be possible to redesign into a lower strength material more economically.
Let’s assume you plan to use a 3-inch thick pad of ETHAFOAM 220 to cushion a side of your product, which presents a static load of 10 psi. You’d refer to Buckling Coefficients for ETHAFOAM 220 at Various Static Loadings, find 1.0 psi along the bottom and follow the vertical line straight up until it intersects the plot line. From this point, follow the horizontal line to the left where you’ll find the W/T coefficient. In this case, the coefficient is 0.7. Using the formula T x W/T = W, you can now find the minimum width: 3"x 0.7 = 2.1". Your cushion must be at least 2.1 inches wide or long to resist buckling.
Note: For higher strength, higher density ETHAFOAM products, the use of a 0.75 buckling coefficient is recommended.

Consider Extreme Temperature Effects

One of the advantages of ETHAFOAM* polyethylene foams is that they retain their properties and characteristics with minimal change over a wide range of temperatures. However, as with all thermoplastic foams, when they are exposed to extremely high or low temperatures over a considerable length of time, they may be affected. The materials become stiffer at low temperatures and increasingly softer at higher temperatures. In extreme cases, it may become necessary to compensate for these effects in your design. Consult the individual product data sheets for ETHAFOAM available data on cushioning performance at extreme temperatures.

STEP FIVE: Design Prototypes and Test

Certainly no specific recommendations can be made about how to fabricate and position the foam on or around a particular product. Each packaging design must be developed separately, given the large number of variables involved.
The functional foam determinations made in conjunction with dynamic cushioning curves of ETHAFOAM* products, does not account for any protective contribution made by an outer container. It also does not account for effects such as shear and friction within the container, all of which may enhance the performance of the design to lower shock levels than those indicated by dynamic cushioning curves.
For this reason, it is highly recommended that you build and test a prototype of your cushion design to determine its actual performance. In many cases you will find that its performance exceeds your needs and, based on prototype testing, you can cut back on the amount of ETHAFOAM in the pack even further for an even more economical pack design. Any such modified designs should also then be tested to verify their performance.
Performance testing of prototype packages designed with ETHAFOAM polyethylene foam products is one of the services available from our research center. For more information, contact our technical staff at (800) 441-4369, or your local Dow-authorized fabricator.

STEP SEVEN: Monitor Performance

If it works, question it
There are many assumptions that went into your design development, among them that the drop height likely to be encountered is realistic, and that the fragility value used is representative of the product actually being packaged. Even when you are lucky enough to be working with a fragility value that was obtained by actual testing, in many cases what was tested was a prototype, and the production units may be more or less rugged than indicated.
For these reasons, it is a good practice to monitor the performance of your design in actual use. This will help you to determine if your design is providing more real-world performance than is actually required, or not enough. It can also allow you to determine when internal changes in the design of the packaged product might alter the requirements for package performance.
Just as no shipper can afford high damage rates, neither can he afford to overpackage. Monitoring of packaging performance on an ongoing basis can also help determine if further economies can be achieved without sacrificing protection.